Occurrence of Metals
Most metals are found in the earth’s crust in a combined form, and we have to extract them into their pure form, as they are very useful to us. This is again a very important topic, and you should read it thoroughly. This involves three parts – enrichment of ore, reduction to obtain metal, and refining/purification.
We will study this in 3 parts:
Extracting Metals Low in the Activity Series – These metals are very unreactive, and these metals can be extracted by heating alone. For example, Hg and Cu :
2HgS(s)+3O2(g)–>2HgO(s)+2SO2(g)
2HgO(s)—>2Hg(l)+O2(g)
Extracting Metals in the middle of the Activity Series – Metals present in this category are extracted by various processes. This topic is very important from exam point of view, so make sure you study this thoroughly. To revise this topic thoroughly, click on the card that you see on your screen.
Extracting Metals towards the top in the Activity Series – Highly reactive metals like sodium, calcium, aluminium etc are extracted from their molten chloride solution using electrolysis.
Let us take an example. If we want to extract sodium from molten sodium chloride solution, the reactions that take place are:
At cathode: Na++e–→Na
At anode: 2Cl–→Cl2+2e–
The metal is deposited at the cathode (the negatively charged electrode), whereas, chlorine is liberated at the anode (the positively charged electrode).

After extraction, metals have to be purified. This is done by the process of electrolytic refining. In this process, impure metal is made the anode and a thin strip of pure metal is made the cathode. A solution of the metal salt is used as an electrolyte. On passing the current through the electrolyte, the pure metal from the anode dissolves into the electrolyte. An equivalent amount of pure metal from the electrolyte is deposited on the cathode. The soluble impurities go into the solution, whereas, the insoluble impurities settle down at the bottom of the anode and are known as anode mud.